首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   35112篇
  免费   5778篇
  国内免费   3777篇
化学   25307篇
晶体学   451篇
力学   2118篇
综合类   268篇
数学   3995篇
物理学   12528篇
  2024年   38篇
  2023年   760篇
  2022年   779篇
  2021年   1197篇
  2020年   1489篇
  2019年   1388篇
  2018年   1162篇
  2017年   1064篇
  2016年   1673篇
  2015年   1667篇
  2014年   1861篇
  2013年   2489篇
  2012年   3129篇
  2011年   3251篇
  2010年   2156篇
  2009年   2012篇
  2008年   2343篇
  2007年   2147篇
  2006年   1934篇
  2005年   1754篇
  2004年   1265篇
  2003年   1089篇
  2002年   1029篇
  2001年   788篇
  2000年   710篇
  1999年   792篇
  1998年   576篇
  1997年   531篇
  1996年   468篇
  1995年   457篇
  1994年   442篇
  1993年   375篇
  1992年   294篇
  1991年   284篇
  1990年   266篇
  1989年   187篇
  1988年   151篇
  1987年   143篇
  1986年   109篇
  1985年   102篇
  1984年   82篇
  1983年   42篇
  1982年   41篇
  1981年   37篇
  1980年   23篇
  1979年   8篇
  1976年   11篇
  1975年   14篇
  1971年   7篇
  1957年   6篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
The coordination chemistry of f-block elements (lanthanide and actinide) in molten salts has become a resounding topic in view of its great importance to the research and development (R&D) of molten salt reactors and pyroprocessing. In this Review article, a general overview of the coordination chemistry of f-block elements in molten salts is provided including past achievements and recent advances. Particular emphases are placed on the oxidation state, speciation, and solution structure of f-block metal ions in molten salts, as well as their relationships with the salt composition. Furthermore, this review briefly discusses the spectroscopic and theoretical methods that complement each other in revealing the coordination properties.  相似文献   
2.
At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time-of-flight mass spectrometer (MB-VUV-PI-TOFMS) was applied to study the low-temperature oxidation of cyclopentane (CPT) at a total pressure range from 1–3 atm and low-temperature range between 500 and 800 K. Low-temperature reaction products including cyclic olefins, cyclic ethers, and highly oxygenated intermediates (e. g., ketohydroperoxide KHP, keto-dihydroperoxide KDHP, olefinic hydroperoxides OHP and ketone structure products) were observed. Further investigation of the oxidation of CPT – electronic structure calculations – were carried out at the UCCSD(T)-F12a/aug-cc-pVDZ//B3LYP/6-31+ G(d,p) level to explore the reactivity of O2 molecules adding sequentially to cyclopentyl radicals. Experimental and theoretical observations showed that the dominant product channel in the reaction of CPT radicals with O2 is HO2 elimination yielding cyclopentene. The pathways of second and third O2 addition – the dissociation of hydroperoxide – were further confirmed. The results of this study will develop the low-temperature oxidation mechanism of CPT, which can be used for future research on accurately simulating the combustion process of CPT.  相似文献   
3.
Tian  Xiu-Zhi  Yang  Rui  Ma  Jia-Jia  Ni  Yong-Hao  Deng  Hai-Bo  Dai  Lei  Tan  Jiao-Jun  Zhang  Mei-Yun  Jiang  Xue 《高分子科学》2022,40(7):789-798
Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was...  相似文献   
4.
Xu  Feixiang  Luo  Jiangchen  Jiang  Liqun  Zhao  Zengli 《Cellulose (London, England)》2022,29(3):1463-1472
Cellulose - In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis...  相似文献   
5.
Wang  Rong  Li  Xu  Zhou  Youshi  Cao  Shuxuan  Xu  Honghao  Han  Wenjuan  Zhang  Yuxia  Liu  Junhai 《Journal of Russian Laser Research》2022,43(4):476-481
Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The...  相似文献   
6.
International Journal of Theoretical Physics - In this work, we give an analytical derivation of the reduced density matrix between two qubits in a cavity field, which is described by the quantum...  相似文献   
7.
8.
蒋峰景  宋涵晨 《化学进展》2022,34(6):1290-1297
液流电池是一种安全性高、使用寿命长、可扩展的大规模储能系统,可以协助电网调峰储能,提高能源利用率,发展前景广阔。双极板是液流电池的重要组成部分。功能上起到了分隔、串联电池、传导电流、为电堆提供结构支撑等作用。从成本构成角度看,双极板的价格占电堆成本的比重也较大。开发高性能、低成本的双极板对加快液流电池的商业化应用具有重要意义,也是目前业界的迫切需求。虽然文献上报道了许多针对液流电池双极板开发的工作,但是目前高性能、低成本的液流电池双极板产品仍无法充分满足市场需求。本文着重介绍了石墨基复合双极板的研究现状,介绍了材料选择、工艺流程对关键性能的影响,对相关工作进行了评述,并为液流电池双极板的开发提出了建议。  相似文献   
9.
Solar-driven interfacial vaporization by localizing solar-thermal energy conversion to the air−water interface has attracted tremendous attention. In the process of converting solar energy into heat energy, photothermal materials play an essential role. Herein, a flexible solar-thermal material di-cyan substituted 5,12-dibutylquinacridone (DCN−4CQA)@Paper was developed by coating photothermal quinacridone derivatives on the cellulose paper. The DCN−4CQA@Paper combines desired chemical and physical properties, broadband light-absorbing, and shape-conforming abilities that render efficient photothermic vaporization. Notably, synergetic coupling of solar-steam and solar-electricity technologies by integrating DCN−4CQA@Paper and the thermoelectric devices is realized without trade-offs, highlighting the practical consideration toward more impactful solar heat exploitation. Such solar distillation and low-grade heat-to-electricity generation functions can provide potential opportunities for fresh water and electricity supply in off-grid or remote areas.  相似文献   
10.
International Journal of Theoretical Physics - Quantum logic gates are the foundation of circuit-based quantum computation and quantum simulation. Multi-qubit quantum controlled gates are of vital...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号